Di-n-octyltin oxide (DOTO) plays a vital role in the plastics industry, especially in During the processing and stabilization of polyvinyl chloride (PVC). As a highly efficient organotin compound, it not only provides excellent thermal stability and processing performance, but also improves the physical and chemical properties of the product to a certain extent. The following are several key roles of dioctyltin oxide in the plastics industry, especially in the production of PVC products:
Heat stabilizer
PVC is prone to dehydrochlorination under heating conditions, leading to chain breakage and yellowing, seriously affecting its mechanical properties and appearance. As a thermal stabilizer, dioctyltin oxide can capture the released HCl and prevent it from further catalyzing the degradation reaction, thereby inhibiting the thermal degradation process of PVC. By providing a stable environment, it avoids further attack by HCl on the PVC molecular chain, extending the service life of the product and maintaining the transparency of the product.
Chain transfer agent
In addition to thermal stabilization, dioctyltin oxide also acts as a chain transfer agent. During the polymerization and processing of PVC, it can regulate the growth of the polymer chain, reduce the formation of unstable ends through chain transfer, thereby improving the fluidity of PVC, making the processing process smoother, and also helping to control the polymer properties. molecular weight distribution to optimize product performance.
Antioxidants
Dioctyltin oxide also shows certain antioxidant properties, which can resist the attack of hot oxygen and ultraviolet rays on PVC to a certain extent, improving the weather resistance and anti-aging capabilities of the product. This is particularly important for PVC products used outdoors, as they are often exposed to harsh environmental conditions.
steric hindrance effect
The long chain structure of dioctyltin oxide gives it good steric hindrance effect, which helps protect PVC molecules from damage by external factors. The steric hindrance effect can prevent harmful substances from directly contacting the PVC molecular chain, thereby acting as a physical barrier and further enhancing the stability of PVC.
Improve processing performance
In PVC processing, dioctyltin oxide can improve the plasticizing properties of the material, reduce the melting temperature, shorten the processing cycle, and improve production efficiency. This not only saves energy consumption, but also reduces production costs and improves economic benefits.
Structural Characteristics
The chemical formula of dioctyltin oxide is C16H34OSn. Its molecular structure contains two octyl chains and one tin oxide group. This special structure not only has good lipophilicity, but also can be evenly dispersed in the plastic matrix, ensuring the full play of its stabilizer function.
Application fields
Dioctyltin oxide is widely used in PVC soft products, hard products, and various PVC films, pipes, plates, wire and cable sheaths and other products. From PVC pipes used in construction to plastic packaging common in daily life, to automotive interior parts, dioctyltin oxide is one of the indispensable additives.
Safety and environmental protection
Although the application of dioctyltin oxide in the plastics industry has brought many benefits, its potential environmental and health risks also need to be taken into account. As an organotin compound, it may be harmful to aquatic life and is a potential threat to human health at high concentrations. As a result, the industry is constantly exploring safer and greener alternatives to reduce environmental impact while meeting increasingly stringent regulatory requirements.
In short, dioctyltin oxide is used in the plastics industry, especially in the production of PVC products, to ensure product quality, extend service life and improve processing Key ingredients for performance. However, its use also needs to be cautious to balance the relationship between economic benefits and environmental protection. With the development of green chemistry, finding more sustainable solutions will be an important trend in the plastics industry in the future.
Extended reading:
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stannous neodecanoate catalysts – Amine Catalysts (newtopchem.com)
polyurethane tertiary amine catalyst/Dabco 2039 catalyst – Amine Catalysts (newtopchem.com)
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